Wednesday, May 3, 2023

α-Lactam Electrophiles for Covalent Chemical Biology

Mahía, AlejandroKiib, AndersNisavíc, MarijaSvenningsen, EsbenPalmfeldt, JohanPoulsen, Thomas BjørnskovAngew. Chem. Int. Ed. 2023, e202304142

https://doi.org/10.1002/anie.202304142

Electrophilic groups are one of the key pillars of contemporary chemical biology and medicinal chemistry. For instance, the group of 3-membered N-heterocyclic compounds – such as aziridines, azirines, and oxaziridines – possess unique electronic and structural properties which underlie their potential and applicability as covalent tools. The α-lactams are also members of this group of compounds, however, their utility within the field remains unexplored. Here, we demonstrate an α-lactam reagent (AM2) that is tolerant to aqueous buffers while being reactive towards biologically relevant nucleophiles. Interestingly, carboxylesterases 1 and 2 (CES1/2), both serine hydrolases with key roles in endo- and xenobiotic metabolism, were found as primary covalent targets for AM2 in HepG2 liver cancer cells. All in all, our study constitutes the starting point for the further development and exploration of α-lactam-based electrophilic probes in covalent chemical biology.



Discovery of a Tunable Heterocyclic Electrophile 4-Chloro-pyrazolopyridine That Defines a Unique Subset of Ligandable Cysteines

Hong-Rae Kim, David P. Byun, Kalyani Thakur, Jennifer Ritchie, Yixin Xie, Ronald Holewinski, Kiall F. Suazo, Mckayla Stevens, Hope Liechty, ...